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王笃金研究员

董金勇研究员

阳明书研究员

孙文华研究员

甘志华研究员

李春成研究员

刘琛阳研究员

张  军研究员

资深科学家

胡友良研究员

何嘉松研究员

 

新闻

工程塑料实验室开展与神华宁煤集团技术合作交流活动(2010.06.30)

2009年度工程塑料实验室工作考核报告结果(2009.12.11)

第四届工程塑料国际研讨会成功召开(2009.09.01)

实验室开展与英国Bradford大学学术交流和合作(2009.04.01)

2008年度工程塑料实验室工作考核报告结果(2008.12.04)

实验室开展与青岛大学学术交流和合作(2008.11.04)

实验室开展与英国Bradford大学学术交流和合作(2008.10.07)

董金勇研究员荣获第五届“柳大纲优秀青年科技奖”(2008.07.03)

化学所新一届所领导班子成立(2008.03.31)

我室何嘉松研究员获得“Paul J. Flory Polymer Research Prize”(2008.02.26)

我室承担一项目获奖(2007.12.04)

2007年度工程塑料实验室工作考核报告结果(2007.11.30)

研究进展

Solid-State NMR Characterization of the Multiphase Structure of Polypropylene In-reactor Alloy, Zhu HJ, Graf R*, Hou GJ, Zhao Y, Wang DJ*, Spiess HW, MACROMOLECULAR CHEMISTRY AND PHYSICS 211(10): 1157-1166, 2010

Syntheses, Characterization, and Ethylene (Co-)Polymerization Screening of Amidate Half-Titanocene Dichlorides, Liu SF, Sun WH*, Zeng YN, Wang D, Zhang WJ, Li Y, ORGANOMETALLICS 29(11): 2459-2464, 2010

SYNTHESIS OF TERPYRIDINE-FUNCTIONALIZED POLY(N-ISOPROPYLACYLAMIDE)S AND THEIR METAL COMPLEXES, Sun PJ, Shi XD, Gan ZH*, ACTA POLYMERICA SINICA (4): 383-389, 2010

Influence of chemical structure on enzymatic degradation of single crystals of PCL-b-PEO amphiphilic block copolymer, Jiang N, Jiang SD, Hou Y, Yan SK, Zhang GZ, Gan ZH*, POLYMER 51(11): 2426-2434, 2010

Phase Transition and Rheological Behaviors of Concentrated Cellulose/Ionic Liquid Solutions, Song HZ, Zhang J, Niu YH*, Wang ZG*, JOURNAL OF PHYSICAL CHEMISTRY B 114(18): 6006-6013, 2010

(eta(3)-Azaallyl)zirconium Chlorides: Synthesis, Characterization, and Ethylene (Co-)polymerization Activity, Yuan SF, Bai SD, Liu DS*, Sun WH*, ORGANOMETALLICS 29(9): 2132-2138, 2010

mu(2),eta(1)-N-[(N,N-Dimethylamino)dimethylsilyl]-2,6-diisopropylanilido Metal (Li, Zr, Hf) Compounds and the Catalytic Behaviors of the IVB Compounds in Ethylene (Co)Polymerization, Yuan SF, Wei XH, Tong HB, Zhang LP, Liu DS*, Sun WH*, ORGANOMETALLICS 29(9): 2085-2092, 2010

Effects of Silane Grafting on the Morphology and Thermal Stability of Poly(ethylene terephthalate)/Clay Nanocomposites, Xu XF, Ding YF, Wang F, Wen B, Zhang JH, Zhang SM, Yang MS*, POLYMER COMPOSITES 31(5): 825-834, 2010

SYNTHESIS OF STYRYL-CAPPED ISOTACTIC POLYPROPYLENES AND THEIR APPLICATION IN SYNTHESIS OF POLYPROPYLENES WITH TOPOLOGICAL STRUCTURE, Huang HH, Dong JY*, ACTA POLYMERICA SINICA (1): 87-95, 2010

Biodegradable amphiphilic block copolymers containing functionalized PEO blocks: Controlled synthesis and biomedical potentials, Zhang Y, Sun PJ, Gan ZH*, SCIENCE CHINA-CHEMISTRY 53(3): 519-527, 2010

Ferrous and Cobaltous Chlorides Bearing 2,8-Bis(imino)quinolines: Highly Active Catalysts for Ethylene Polymerization at High Temperature, Zhang S, Sun WH*, Xiao TP, Hao X, ORGANOMETALLICS 29(5): 1168-1173, 2010

2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization, Zhang M, Zhang WJ, Xiao T, Xiang JF, Hao X, Sun WH*, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 320(1-2): 92-96, 2010

N-(Pyridin-2-yl)picolinamide tetranickel clusters: Synthesis, structure and ethylene oligomerization, Wang KF, Shen M, Sun WH*, POLYHEDRON 29(1): 564-568, 2010

Syntheses, Characterization, and the Ethylene (Co-)Polymerization Screening of 2-Benzimidazolyl-N-phenylquinoline-8-carboxamide Half-Titanocene Chlorides, Sun WH*, Liu SF, Zhang WJ, Zeng YN, Wang D, Liang TL, ORGANOMETALLICS 29(4): 732-741, 2010

Investigation on the Melt Spinning Fibers of PP/Organoclay Nanocomposites Prepared by In-Situ Polymerization, Hao CW, Zhao Y*, He AH, Zhang XQ, Wang DJ, Ma QF, Xu YZ, JOURNAL OF APPLIED POLYMER SCIENCE 116(3): 1384-1391, 2010

Multiple Relaxation Behavior of Long Chain Branched Polylactic Acid, Wang YB, Niu YH, Yang L, Yu FY, Zhang HB, Wang ZG*, CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 31(2): 397-401, 2010

Synthesis of Novel Catalyst Based on TiO2/SiO2 for Poly(ethylene terephthalate), Yin M, Feng RC, Li CC*, Guan GH, Zhang D, Xiao YN, CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 31(2): 418-420, 2010

Ferrous and Cobaltous Chlorides Bearing 2,8-Bis(imino)quinolines: Highly Active Catalysts for Ethylene Polymerization at High Temperature, Zhang S, Sun WH*, Xiao, Hao X, ORGANOMETALLICS 29(5): 1168-1173, 2010

Crystallization and morphological control of calcium carbonate by functionalized triblock copolymers, Su YL, Yang HR, Shi WX, Guo HX, Zhao Y, Wang DJ*, COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 355(1-3): 158-162, 2010

Ethylene Polymerization Initiated by Tertiary Diamine/n-Butyllithium Complexes: An Interpretation from Density Functional Theory Study, Li HY*, Zhang LY, Wang ZX*, Hu YL, JOURNAL OF PHYSICAL CHEMISTRY A 114(7): 2697-2700, 2010

Syntheses, Characterization, and the Ethylene (Co-)Polymerization Screening of 2-Benzimidazolyl-N-phenylquinoline-8-carboxamide Half-Titanocene Chlorides, Sun WH*, Liu SF, Zhang WJ, Zeng YN, Wang D, Liang TL, ORGANOMETALLICS 29(4): 732-741, 2010

Dialkylzinc Compounds as Chain Transfer Agents in Ethylene and Propylene Polymerizations Catalyzed by Metallocene Catalysts, Zhang CH, Dong JY*, JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY 47(4): 324-328, 2010

Morphology, rheology and crystallization behavior of polylactide composites prepared through addition of five-armed star polylactide grafted multiwalled carbon nanotubes, Xu ZH, Niu YH, Yang L, Xie WY, Li H, Gan ZH, Wang ZG*, POLYMER 51(3): 730-737, 2010

N-(Pyridin-2-yl)picolinamide tetranickel clusters: Synthesis, structure and ethylene oligomerization, Wang KF, Shen M, Sun WH*, POLYHEDRON 29(1): 564-568, 2010

Solid-Solid Phase Transition of n-Alkanes in Multiple Nanoscale Confinement, Jiang K*, Xie BQ*, Fu DS*, Luo FL*, Liu GM*, Su YL*, Wang DJ, JOURNAL OF PHYSICAL CHEMISTRY B 114(3): 1388-1392, 2010

2-(1H-2-Benzimidazolyl)-6-(1-(arylimino)ethyl)pyridylnickel Complexes: Synthesis, Characterization, and Ethylene Oligomerization, Xiao LW, Zhang M, Gao R, Cao XP, Sun WH*, AUSTRALIAN JOURNAL OF CHEMISTRY 63(1): 109-115, 2010

Biodegradable Polymeric Microcarriers with Controllable Porous Structure for Tissue Engineering, Shi XD, Sun L, Jiang J, Zhang XL, Ding WJ, Gan ZH*, MACROMOLECULAR BIOSCIENCE 9(12): 1211-1218, 2009

Free volume and crystallinity of poly(ethylene naphthalate) treated in pressurized carbon dioxide, Andersson A, Zhai WT, Yu J, He JS*, Maurer FHJ*, POLYMER 51(1): 146-152, 2010

Investigation on Photooxidative Degradation of Polypropylene/Organomontmorillonite Nanocomposites, Zhou LJ, Zhao Y, Yang MS, Wang DJ*, Xu DF, SPECTROSCOPY AND SPECTRAL ANALYSIS 30(1): 109-113, 2010

Novel Catalysts Based on Titanium Dioxide/Silicon Dioxide for Poly(ethylene terephthalate), Yin M, Li CC*, Guan GH, Zhang D, Xiao YN, JOURNAL OF APPLIED POLYMER SCIENCE 115(4): 2470-2478, 2010

Probing into the pristine basic morphology of high impact polypropylene particles, Zhou Y, Niu H, Kong L, Zhao Y, Dong JY*, Wang DJ*, POLYMER 50(19): 4690-4695, 2009

Linear Relationship Between the Partial Charges of H and O Atoms in Carboxyl of Substituted Benzoic Acid and the Hammett Constants, Li HY*, Hu YL, CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 30(11): 2233-2239, 2009

Amphiphilic PEG-co-PGL-g-PCL Copolymer Brushes: Synthesis, Micellization and Controlled Drug Delivery, Mao J, Gan ZH*, MACROMOLECULAR CHEMISTRY AND PHYSICS 210(23): 2078-2086, 2009

Nickel complexes bearing 2-(1H-benzo[d]imidazol-2-yl)-N-benzylidenequinolin-8-amines: Synthesis, structure and catalytic ethylene oligomerization, Wang KF, Gao R, Hao X, Sun WH*, CATALYSIS COMMUNICATIONS 10(13): 1730-1733, 2009

Iron(III) complexes bearing 2-(benzimidazole)-6-(1-aryliminoethyl)pyridines: Synthesis, characterization and their catalytic behaviors towards ethylene oligomerization and polymerization, Hao P, Chen YJ, Xiao TPF, Sun WH*, JOURNAL OF ORGANOMETALLIC CHEMISTRY 695(1): 90-95, 2009

The Influence of Pendant Hydroxyl Groups on Enzymatic Degradation and Drug Delivery of Amphiphilic Poly[glycidol-block-(epsilon-caprolactone)] Copolymers, Mao J, Gan ZH*, MACROMOLECULAR BIOSCIENCE 9(11): 1080-1089, 2009

Confinement Effects on Chain and Glass Dynamics in Immiscible Polymer Blends, Liu CY*, Zhang BQ, He JS, Keunings R, Bailly C, MACROMOLECULES 42(20): 7982-7985, 2009

Criteria of Process Optimization in Binary Polymer Blends with Both Phase Separation and Crystallization, Niu YH, Yang L, Wang H, Wang ZG*, MACROMOLECULES 42(20): 7623-7626, 2009

Synthesis and characterization of organoaluminum compounds containing quinolin-8-amine derivatives and their catalytic behaviour for ring-opening polymerization of epsilon-caprolactone, Shen M, Zhang WJ, Nomura K, Sun WH*, DALTON TRANSACTIONS (241): 9000-9009, 2009

New polypropylene blends toughened by polypropylene/poly(ethylene-co-propylene) in-reactor alloy: Compositional and morphological influence on mechanical properties, Li RB, Zhang XQ, Zhao Y, Hu XT, Zhao XT, Wang DJ*, POLYMER 50(21): 5124-5133, 2009

Bridged bis-pyridinylimino dinickel(II) complexes: Syntheses, characterization, ethylene oligomerization and polymerization, Jie SY, Zhang DH, Zhang TZ, Sun WH*, Chen JT, Ren Q, Liu DB, Zheng G, Chen W*, JOURNAL OF ORGANOMETALLIC CHEMISTRY 690(7): 1739-1749, 2009

Nickel complexes bearing 2-(1H-benzo[d]imidazol-2-y1)-N-benzylidenequinolin-8-amines: Synthesis, structure and catalytic ethylene oligomerization, Wang KF, Gao R, Hao X, Sun WH*, CATALYSIS COMMUNICATIONS 10(13): 1730-1733, 2009

Chromium(III) complexes bearing 2-benzoxazolyl-6-arylimino-pyridines: Synthesis and their ethylene reactivity, Gao R, Liang TL, Wang FS, Sun WH*, JOURNAL OF ORGANOMETALLIC CHEMISTRY 694(23): 3701-3707, 2009

Polymer reptation for molecular assembly of copper phthalocyanine, Duan XL, Tang QX, Qiu J, Niu YH, Wang ZG*, Hu WP*, APPLIED PHYSICS LETTERS 95(11): 113301, 2009

Morphologies, crystallinity and dynamic mechanical characterizations of polypropylene/polystyrene blends compatibilized with PP-g-PS copolymer: Effect of the side chain length, Li JG, Li HY*, Wu CH, Ke YC, Wang DJ, Li Q, Zhang LY, Hu YL, EUROPEAN POLYMER JOURNAL 45(9): 2619-2628, 2009

Syntheses, Structures, and Fluorescent Properties of 2-(1H-Imidazol-2-yl)phenols and Their Neutral Zn(II) Complexes, Eseola AO, Li W, Gao R, Zhang M, Hao X, Liang TL, Obi-Egbedi NO, Sun WH*, INORGANIC CHEMISTRY 48(19): 9133-9146, 2009

Influence of Montmorillonite Treatment and Montmorillonite Dispersion State on the Crystallization Behavior of Poly(ethylene terephthalate)/Montmorillonite Nanocomposites, Yin M, Li CC*, Guan GH, Zhang D, Xiao YN, JOURNAL OF APPLIED POLYMER SCIENCE 114(4): 2327-2338, 2009

Crystallization Behavior and Crystallization Kinetic Studies of Isotactic Polypropylene Modified by Long-Chain Branching Polypropylene, Ni Q, Fan JQ, Dong JY*, JOURNAL OF APPLIED POLYMER SCIENCE 114(4): 2180-2194, 2009

THE INFLUENCE OF SUBSTITUENT ELECTRONIC EFFECT ON ETHYLENE OLIGOMERIZATION ACTIVITIES OF BIS(IMINO)PYRIDYL Fe(II) CATALYSTS: A COMBINED MOLECULAR MECHANICS AND CHARGE EQUILIBRATION METHOD, Li HY*, Duan BG, Hu YL, CHINESE JOURNAL OF POLYMER SCIENCE 27(5): 711-717, 2009

Preparation of nearly monodisperse microcapsules with controlled morphology by in situ polymerization of a shell layer, Liu GM, Xie BQ, Fu DS, Wang Y, Fu Q, Wang DJ*, JOURNAL OF MATERIALS CHEMISTRY 19(36): 6605-6609, 2009

Integrated polymer spherulites growing from one homogeneous nucleation site in supercritical fluid, Wang CM, Zhao Y, Song JL, Han BX, Wang DJ*, NEW JOURNAL OF CHEMISTRY 33(9): 1841-1844, 2009

Effect of the Grafted Silane on the Dispersion and Orientation of Clay in Polyethylene Nanocomposites, Qian ZZ, Zhou H, Xu XF, Ding YF, Zhang SM, Yang MS*, POLYMER COMPOSITES 30(9): 1234-1242, 2009

Evolutions of Morphology and Crystalline Ordering Upon Annealing of Quenched Isotactic Polypropylene, Zhao JC, Qiu J, Niu YH, Wang ZG*, JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS 47(17): 1703-1712, 2009

An innovative method to improve the electrical conductivity of multi-walled carbon nanotubes filled polyamide 6/polystyrene blends, Yan DG, Yang MS*, MATERIALS LETTERS 63(22): 1900-1903, 2009

Influence of ethanol addition on the modification of montmorillonite by hexadecyl trimethylammonium bromide, Feng XY, Hu GJ, Meng XF, Ding YF, Zhang SM, Yang MS*, APPLIED CLAY SCIENCE 45(4): 239-243, 2009

2-Benzoxazolyl-6-(1-(arylimino)ethyl)pyridyl cobalt (II) chlorides: A temperature switch catalyst in oligomerization and polymerization of ethylene, Gao R, Wang KF, Li Y, Wang FS, Sun WH*, Redshaw C, Bochmann M, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 309(1-2): 166-171, 2009

Nickel complexes bearing 2-(1H-benzo[d]imidazol-2-y1)-N-benzylidenequinolin-8-amines: Synthesis, structure and catalytic ethylene oligomerization, Wang KF, Gao R, Hao X, Sun WH*, CATALYSIS COMMUNICATIONS 10(13): 1730-1733, 2009

Chromium(III) complexes bearing 2-benzazole-1,10-phenanthrolines: synthesis, molecular structures and ethylene oligomerization and polymerization, Zhang M, Wang KF, Sun WH*, DALTON TRANSACTIONS (32): 6354-6363, 2009

In-Situ Synthesis of Poly(Ethylene Terephthalate)/Clay Nanocomposites Using TiO2/SiO2 Sol-Intercalated Montmorillonite as Polycondensation Catalyst, Yin M, Li CC*, Guan GH, Yuan XP, Zhang D, Xiao YN, POLYMER ENGINEERING AND SCIENCE 49(8): 1562-1572, 2009

Anomalous rheological behavior of poly(1-vinyl-2-pyrrolidone) and CuCl2 in solution and their interactions in solid composites, Hao CW*, Zhao Y*, Dong X, Zhou Y, Xu YZ, Wang DJ, Lai GQ, Jiang JX, POLYMER INTERNATIONAL 58(8): 906-911, 2009

Synthesis, characterization and properties of biodegradable poly(butylene succinate)-block-poly(propylene glycol) segmented copolyesters, Huang X, Li CC, Zheng LC, Zhang D, Guan GH, Xiao YN*, POLYMER INTERNATIONAL 58(8): 893-899, 2009

PROGRESS OF NICKEL COMPLEXES AS CATALYSTS FOR ETHYLENE OLIGOMERIZATION/POLYMERIZATION, Zhang M, Xiao TPF, Sun WH*, ACTA POLYMERICA SINICA (7): 600-612, 2009

Investigation on Phase Separation Kinetics of Polyolefin Blends through Combination of Viscoelasticity and Morphology, Niu YH, Yang L, Shimizu K, Pathak JA, Wang H, Wang ZG*, JOURNAL OF PHYSICAL CHEMISTRY B 113(26): 8820-8827, 2009

Dendritic Effect on Supramolecular Self-Assembly: Organogels with Strong Fluorescence Emission Induced by Aggregation, Chen YL, Lv YX, Han Y, Zhu B, Zhang F, Bo ZS*, Liu CY*, LANGMUIR 25(15): 8548-8555, 2009

Thermal degradation of star-shaped poly(epsilon-caprolactone), XIe WY, Gan ZH*, POLYMER DEGRADATION AND STABILITY 94(7): 1040-1046, 2009

Hydrodebromination of bromoarenes using Grignard reagents catalyzed by metal ions, Shen M, Sun WH*, APPLIED ORGANOMETALLIC CHEMISTRY 23(2): 51-54, 2009

Effects of spinodal decomposition on mechanical properties of a polyolefin blend from high to low strain rates, Yang L, Niu YH*, Wang H, Wang ZG*, POLYMER 50(13): 2990-2998, 2009

Facile synthesis of elongated calcite superstructure by triblock copolymers with precisely designed block length, Su YL, Wang DX, Yang HR, Wang DJ*, COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 342(1-3): 122-126, 2009

2-(1H-2-Benzimidazolyl)-6-(1-(arylimino)ethyl)pyridyl Iron(II) and Cobalt(II) Dichlorides: Syntheses, Characterizations, and Catalytic Behaviors toward Ethylene Reactivity, Xiao LW, Gao R, Zhang M, Li Y, Cao XP*, Sun WH*, ORGANOMETALLICS 28(7): 2225-2233, 2009

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