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新闻

工程塑料实验室开展与神华宁煤集团技术合作交流活动(2010.06.30)

2009年度工程塑料实验室工作考核报告结果(2009.12.11)

第四届工程塑料国际研讨会成功召开(2009.09.01)

实验室开展与英国bradford大学学术交流和合作(2009.04.01)

2008年度工程塑料实验室工作考核报告结果(2008.12.04)

实验室开展与青岛大学学术交流和合作(2008.11.04)

实验室开展与英国bradford大学学术交流和合作(2008.10.07)

董金勇研究员荣获第五届“柳大纲优秀青年科技奖”(2008.07.03)

化学所新一届所领导班子成立(2008.03.31)

我室何嘉松研究员获得“paul j. flory polymer research prize”(2008.02.26)

我室承担一项目获奖(2007.12.04)

2007年度工程塑料实验室工作考核报告结果(2007.11.30)

研究进展

solid-state nmr characterization of the multiphase structure of polypropylene in-reactor alloy, zhu hj, graf r*, hou gj, zhao y, wang dj*, spiess hw, macromolecular chemistry and physics 211(10): 1157-1166, 2010

syntheses, characterization, and ethylene (co-)polymerization screening of amidate half-titanocene dichlorides, liu sf, sun wh*, zeng yn, wang d, zhang wj, li y, organometallics 29(11): 2459-2464, 2010

synthesis of terpyridine-functionalized poly(n-isopropylacylamide)s and their metal complexes, sun pj, shi xd, gan zh*, acta polymerica sinica (4): 383-389, 2010

influence of chemical structure on enzymatic degradation of single crystals of pcl-b-peo amphiphilic block copolymer, jiang n, jiang sd, hou y, yan sk, zhang gz, gan zh*, polymer 51(11): 2426-2434, 2010

phase transition and rheological behaviors of concentrated cellulose/ionic liquid solutions, song hz, zhang j, niu yh*, wang zg*, journal of physical chemistry b 114(18): 6006-6013, 2010

(eta(3)-azaallyl)zirconium chlorides: synthesis, characterization, and ethylene (co-)polymerization activity, yuan sf, bai sd, liu ds*, sun wh*, organometallics 29(9): 2132-2138, 2010

mu(2),eta(1)-n-[(n,n-dimethylamino)dimethylsilyl]-2,6-diisopropylanilido metal (li, zr, hf) compounds and the catalytic behaviors of the ivb compounds in ethylene (co)polymerization, yuan sf, wei xh, tong hb, zhang lp, liu ds*, sun wh*, organometallics 29(9): 2085-2092, 2010

effects of silane grafting on the morphology and thermal stability of poly(ethylene terephthalate)/clay nanocomposites, xu xf, ding yf, wang f, wen b, zhang jh, zhang sm, yang ms*, polymer composites 31(5): 825-834, 2010

synthesis of styryl-capped isotactic polypropylenes and their application in synthesis of polypropylenes with topological structure, huang hh, dong jy*, acta polymerica sinica (1): 87-95, 2010

biodegradable amphiphilic block copolymers containing functionalized peo blocks: controlled synthesis and biomedical potentials, zhang y, sun pj, gan zh*, science china-chemistry 53(3): 519-527, 2010

ferrous and cobaltous chlorides bearing 2,8-bis(imino)quinolines: highly active catalysts for ethylene polymerization at high temperature, zhang s, sun wh*, xiao tp, hao x, organometallics 29(5): 1168-1173, 2010

2-ethyl-ketimino-1,10-phenanthroline iron(ii) complexes as highly active catalysts for ethylene oligomerization, zhang m, zhang wj, xiao t, xiang jf, hao x, sun wh*, journal of molecular catalysis a-chemical 320(1-2): 92-96, 2010

n-(pyridin-2-yl)picolinamide tetranickel clusters: synthesis, structure and ethylene oligomerization, wang kf, shen m, sun wh*, polyhedron 29(1): 564-568, 2010

syntheses, characterization, and the ethylene (co-)polymerization screening of 2-benzimidazolyl-n-phenylquinoline-8-carboxamide half-titanocene chlorides, sun wh*, liu sf, zhang wj, zeng yn, wang d, liang tl, organometallics 29(4): 732-741, 2010

investigation on the melt spinning fibers of pp/organoclay nanocomposites prepared by in-situ polymerization, hao cw, zhao y*, he ah, zhang xq, wang dj, ma qf, xu yz, journal of applied polymer science 116(3): 1384-1391, 2010

multiple relaxation behavior of long chain branched polylactic acid, wang yb, niu yh, yang l, yu fy, zhang hb, wang zg*, chemical journal of chinese universities-chinese 31(2): 397-401, 2010

synthesis of novel catalyst based on tio2/sio2 for poly(ethylene terephthalate), yin m, feng rc, li cc*, guan gh, zhang d, xiao yn, chemical journal of chinese universities-chinese 31(2): 418-420, 2010

ferrous and cobaltous chlorides bearing 2,8-bis(imino)quinolines: highly active catalysts for ethylene polymerization at high temperature, zhang s, sun wh*, xiao, hao x, organometallics 29(5): 1168-1173, 2010

crystallization and morphological control of calcium carbonate by functionalized triblock copolymers, su yl, yang hr, shi wx, guo hx, zhao y, wang dj*, colloids and surfaces a-physicochemical and engineering aspects 355(1-3): 158-162, 2010

ethylene polymerization initiated by tertiary diamine/n-butyllithium complexes: an interpretation from density functional theory study, li hy*, zhang ly, wang zx*, hu yl, journal of physical chemistry a 114(7): 2697-2700, 2010

syntheses, characterization, and the ethylene (co-)polymerization screening of 2-benzimidazolyl-n-phenylquinoline-8-carboxamide half-titanocene chlorides, sun wh*, liu sf, zhang wj, zeng yn, wang d, liang tl, organometallics 29(4): 732-741, 2010

dialkylzinc compounds as chain transfer agents in ethylene and propylene polymerizations catalyzed by metallocene catalysts, zhang ch, dong jy*, journal of macromolecular science part a-pure and applied chemistry 47(4): 324-328, 2010

morphology, rheology and crystallization behavior of polylactide composites prepared through addition of five-armed star polylactide grafted multiwalled carbon nanotubes, xu zh, niu yh, yang l, xie wy, li h, gan zh, wang zg*, polymer 51(3): 730-737, 2010

n-(pyridin-2-yl)picolinamide tetranickel clusters: synthesis, structure and ethylene oligomerization, wang kf, shen m, sun wh*, polyhedron 29(1): 564-568, 2010

solid-solid phase transition of n-alkanes in multiple nanoscale confinement, jiang k*, xie bq*, fu ds*, luo fl*, liu gm*, su yl*, wang dj, journal of physical chemistry b 114(3): 1388-1392, 2010

2-(1h-2-benzimidazolyl)-6-(1-(arylimino)ethyl)pyridylnickel complexes: synthesis, characterization, and ethylene oligomerization, xiao lw, zhang m, gao r, cao xp, sun wh*, australian journal of chemistry 63(1): 109-115, 2010

biodegradable polymeric microcarriers with controllable porous structure for tissue engineering, shi xd, sun l, jiang j, zhang xl, ding wj, gan zh*, macromolecular bioscience 9(12): 1211-1218, 2009

free volume and crystallinity of poly(ethylene naphthalate) treated in pressurized carbon dioxide, andersson a, zhai wt, yu j, he js*, maurer fhj*, polymer 51(1): 146-152, 2010

investigation on photooxidative degradation of polypropylene/organomontmorillonite nanocomposites, zhou lj, zhao y, yang ms, wang dj*, xu df, spectroscopy and spectral analysis 30(1): 109-113, 2010

novel catalysts based on titanium dioxide/silicon dioxide for poly(ethylene terephthalate), yin m, li cc*, guan gh, zhang d, xiao yn, journal of applied polymer science 115(4): 2470-2478, 2010

probing into the pristine basic morphology of high impact polypropylene particles, zhou y, niu h, kong l, zhao y, dong jy*, wang dj*, polymer 50(19): 4690-4695, 2009

linear relationship between the partial charges of h and o atoms in carboxyl of substituted benzoic acid and the hammett constants, li hy*, hu yl, chemical journal of chinese universities-chinese 30(11): 2233-2239, 2009

amphiphilic peg-co-pgl-g-pcl copolymer brushes: synthesis, micellization and controlled drug delivery, mao j, gan zh*, macromolecular chemistry and physics 210(23): 2078-2086, 2009

nickel complexes bearing 2-(1h-benzo[d]imidazol-2-yl)-n-benzylidenequinolin-8-amines: synthesis, structure and catalytic ethylene oligomerization, wang kf, gao r, hao x, sun wh*, catalysis communications 10(13): 1730-1733, 2009

iron(iii) complexes bearing 2-(benzimidazole)-6-(1-aryliminoethyl)pyridines: synthesis, characterization and their catalytic behaviors towards ethylene oligomerization and polymerization, hao p, chen yj, xiao tpf, sun wh*, journal of organometallic chemistry 695(1): 90-95, 2009

the influence of pendant hydroxyl groups on enzymatic degradation and drug delivery of amphiphilic poly[glycidol-block-(epsilon-caprolactone)] copolymers, mao j, gan zh*, macromolecular bioscience 9(11): 1080-1089, 2009

confinement effects on chain and glass dynamics in immiscible polymer blends, liu cy*, zhang bq, he js, keunings r, bailly c, macromolecules 42(20): 7982-7985, 2009

criteria of process optimization in binary polymer blends with both phase separation and crystallization, niu yh, yang l, wang h, wang zg*, macromolecules 42(20): 7623-7626, 2009

synthesis and characterization of organoaluminum compounds containing quinolin-8-amine derivatives and their catalytic behaviour for ring-opening polymerization of epsilon-caprolactone, shen m, zhang wj, nomura k, sun wh*, dalton transactions (241): 9000-9009, 2009

new polypropylene blends toughened by polypropylene/poly(ethylene-co-propylene) in-reactor alloy: compositional and morphological influence on mechanical properties, li rb, zhang xq, zhao y, hu xt, zhao xt, wang dj*, polymer 50(21): 5124-5133, 2009

bridged bis-pyridinylimino dinickel(ii) complexes: syntheses, characterization, ethylene oligomerization and polymerization, jie sy, zhang dh, zhang tz, sun wh*, chen jt, ren q, liu db, zheng g, chen w*, journal of organometallic chemistry 690(7): 1739-1749, 2009

nickel complexes bearing 2-(1h-benzo[d]imidazol-2-y1)-n-benzylidenequinolin-8-amines: synthesis, structure and catalytic ethylene oligomerization, wang kf, gao r, hao x, sun wh*, catalysis communications 10(13): 1730-1733, 2009

chromium(iii) complexes bearing 2-benzoxazolyl-6-arylimino-pyridines: synthesis and their ethylene reactivity, gao r, liang tl, wang fs, sun wh*, journal of organometallic chemistry 694(23): 3701-3707, 2009

polymer reptation for molecular assembly of copper phthalocyanine, duan xl, tang qx, qiu j, niu yh, wang zg*, hu wp*, applied physics letters 95(11): 113301, 2009

morphologies, crystallinity and dynamic mechanical characterizations of polypropylene/polystyrene blends compatibilized with pp-g-ps copolymer: effect of the side chain length, li jg, li hy*, wu ch, ke yc, wang dj, li q, zhang ly, hu yl, european polymer journal 45(9): 2619-2628, 2009

syntheses, structures, and fluorescent properties of 2-(1h-imidazol-2-yl)phenols and their neutral zn(ii) complexes, eseola ao, li w, gao r, zhang m, hao x, liang tl, obi-egbedi no, sun wh*, inorganic chemistry 48(19): 9133-9146, 2009

influence of montmorillonite treatment and montmorillonite dispersion state on the crystallization behavior of poly(ethylene terephthalate)/montmorillonite nanocomposites, yin m, li cc*, guan gh, zhang d, xiao yn, journal of applied polymer science 114(4): 2327-2338, 2009

crystallization behavior and crystallization kinetic studies of isotactic polypropylene modified by long-chain branching polypropylene, ni q, fan jq, dong jy*, journal of applied polymer science 114(4): 2180-2194, 2009

the influence of substituent electronic effect on ethylene oligomerization activities of bis(imino)pyridyl fe(ii) catalysts: a combined molecular mechanics and charge equilibration method, li hy*, duan bg, hu yl, chinese journal of polymer science 27(5): 711-717, 2009

preparation of nearly monodisperse microcapsules with controlled morphology by in situ polymerization of a shell layer, liu gm, xie bq, fu ds, wang y, fu q, wang dj*, journal of materials chemistry 19(36): 6605-6609, 2009

integrated polymer spherulites growing from one homogeneous nucleation site in supercritical fluid, wang cm, zhao y, song jl, han bx, wang dj*, new journal of chemistry 33(9): 1841-1844, 2009

effect of the grafted silane on the dispersion and orientation of clay in polyethylene nanocomposites, qian zz, zhou h, xu xf, ding yf, zhang sm, yang ms*, polymer composites 30(9): 1234-1242, 2009

evolutions of morphology and crystalline ordering upon annealing of quenched isotactic polypropylene, zhao jc, qiu j, niu yh, wang zg*, journal of polymer science part b-polymer physics 47(17): 1703-1712, 2009

an innovative method to improve the electrical conductivity of multi-walled carbon nanotubes filled polyamide 6/polystyrene blends, yan dg, yang ms*, materials letters 63(22): 1900-1903, 2009

influence of ethanol addition on the modification of montmorillonite by hexadecyl trimethylammonium bromide, feng xy, hu gj, meng xf, ding yf, zhang sm, yang ms*, applied clay science 45(4): 239-243, 2009

2-benzoxazolyl-6-(1-(arylimino)ethyl)pyridyl cobalt (ii) chlorides: a temperature switch catalyst in oligomerization and polymerization of ethylene, gao r, wang kf, li y, wang fs, sun wh*, redshaw c, bochmann m, journal of molecular catalysis a-chemical 309(1-2): 166-171, 2009

nickel complexes bearing 2-(1h-benzo[d]imidazol-2-y1)-n-benzylidenequinolin-8-amines: synthesis, structure and catalytic ethylene oligomerization, wang kf, gao r, hao x, sun wh*, catalysis communications 10(13): 1730-1733, 2009

chromium(iii) complexes bearing 2-benzazole-1,10-phenanthrolines: synthesis, molecular structures and ethylene oligomerization and polymerization, zhang m, wang kf, sun wh*, dalton transactions (32): 6354-6363, 2009

in-situ synthesis of poly(ethylene terephthalate)/clay nanocomposites using tio2/sio2 sol-intercalated montmorillonite as polycondensation catalyst, yin m, li cc*, guan gh, yuan xp, zhang d, xiao yn, polymer engineering and science 49(8): 1562-1572, 2009

anomalous rheological behavior of poly(1-vinyl-2-pyrrolidone) and cucl2 in solution and their interactions in solid composites, hao cw*, zhao y*, dong x, zhou y, xu yz, wang dj, lai gq, jiang jx, polymer international 58(8): 906-911, 2009

synthesis, characterization and properties of biodegradable poly(butylene succinate)-block-poly(propylene glycol) segmented copolyesters, huang x, li cc, zheng lc, zhang d, guan gh, xiao yn*, polymer international 58(8): 893-899, 2009

progress of nickel complexes as catalysts for ethylene oligomerization/polymerization, zhang m, xiao tpf, sun wh*, acta polymerica sinica (7): 600-612, 2009

investigation on phase separation kinetics of polyolefin blends through combination of viscoelasticity and morphology, niu yh, yang l, shimizu k, pathak ja, wang h, wang zg*, journal of physical chemistry b 113(26): 8820-8827, 2009

dendritic effect on supramolecular self-assembly: organogels with strong fluorescence emission induced by aggregation, chen yl, lv yx, han y, zhu b, zhang f, bo zs*, liu cy*, langmuir 25(15): 8548-8555, 2009

thermal degradation of star-shaped poly(epsilon-caprolactone), xie wy, gan zh*, polymer degradation and stability 94(7): 1040-1046, 2009

hydrodebromination of bromoarenes using grignard reagents catalyzed by metal ions, shen m, sun wh*, applied organometallic chemistry 23(2): 51-54, 2009

effects of spinodal decomposition on mechanical properties of a polyolefin blend from high to low strain rates, yang l, niu yh*, wang h, wang zg*, polymer 50(13): 2990-2998, 2009

facile synthesis of elongated calcite superstructure by triblock copolymers with precisely designed block length, su yl, wang dx, yang hr, wang dj*, colloids and surfaces a-physicochemical and engineering aspects 342(1-3): 122-126, 2009

2-(1h-2-benzimidazolyl)-6-(1-(arylimino)ethyl)pyridyl iron(ii) and cobalt(ii) dichlorides: syntheses, characterizations, and catalytic behaviors toward ethylene reactivity, xiao lw, gao r, zhang m, li y, cao xp*, sun wh*, organometallics 28(7): 2225-2233, 2009

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